Product ID:L S HARDENER HMS 15-1107 PART C
MSDS Date:09/15/1987
FSC:8010
NIIN:00N042434
Kit Part:Y
MSDS Number: BSXRF

ADVANCED COATINGS & CHEMICALS

4343 TEMPLE CITY BLVD
TEMPLE CITY, CA 91780
US

Emergency Phone: 818-579-6270

Info Phone: 818-579-6270

Cage: ACTAD

ADVANCED PRODUCTS DBA ADVANCED COATINGS & CHEMICAL

TEMPLE CITY, CA 91780-4229 US

Telephone: 818-579-6270

Cage: 51686

POLYISCOYANTE (POLYMERIC OLIGOMER) CONCS ARE KNOWN

RTECS: 9999999ZZ

(COMBINATION ORGANIC VAPORS AND PARTICULATE) RESP,

RTECS: 9999999ZZ

SPRAY PAINT ENVIRONMENTS, WILL PROVIDE SUFFICIENT

RTECS: 9999999ZZ

KNOWN, OR IF GUIDELINES ARE EXCEEDED, OR IF

RTECS: 9999999ZZ

VENT, THE USE OF NIOSH/MSHA APPRVD POSITIVE PRESSURE

RTECS: 9999999ZZ

OPERATIONS, SUCH AS MIXING, BRUSH OR ROLLER

RTECS: 9999999ZZ

OR ISOCYANATE VAPS. THEREFORE, WHEN AIRBORN CONCS

RTECS: 9999999ZZ

FOR ISOCYANATE MONOMER, BUT <0.2 PPM, @ LST A

RTECS: 9999999ZZ

SOLV CONCS SHLD BE ALSO CONSIDERED WHEN DETERMINING

RTECS: 9999999ZZ

HYGIENE & TOX, VOL I (3RD EDITION) CHAPTER 17 &

RTECS: 9999999ZZ

APPROPRIATE AIR SAMPLING STRATEGY TO DETERMINE

RTECS: 9999999ZZ

KEEP THE AREA COVERED TO A MINIMUM.

RTECS: 9999999ZZ

HEXANE, 1,6-DIISOCYANATO-; (HEXAMETHYLENE DIISOCYANATE)

CAS: 822-06-0

RTECS: MO1740000

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (SARA III)

CAS: 123-86-4

RTECS: AF7350000

OSHA PEL 150 PPM;200 STEL

ACGIH TLV: 150 PPM;200 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL 100 PPM;150 STEL

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WASH DOWN AREA WITH LIQUID DECONTAMINANT AND

RTECS: 9999999ZZ

FROM HEAT, SPARKS AND OPEN FLAME. STORE IN

RTECS: 9999999ZZ

MATLS. AT MAX TEMP NOTED, MATL MAY SLOWLY POLYMERIZE

RTECS: 9999999ZZ

USE 29CFR 1910.134. WHEN THE AIRBORNE ISOCYANATE

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:VAPORS AND MIST: MAY CAUSE IRRIT TO
SKIN, EYES & REP TRACT (NOSE, THROAT & LUNGS). SYMPTOMS MAY BE
WATERING OF EYES, DRYNESS OF THROAT, COUGHING, HEADACHE, TIGHTNESS
IN CHEST OR BURNING SENSATION, DIZ ZINESS OR NAUSEA. RESPIRATORY
SENSITIVITY MAY RESULT IN ASTHMA-LIKE SYMPS. SKIN SENSITIVITY MAY
RSLT (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: IN ALLERGIC DERMATITIS, INCLUDING
RASH, ITCHING, HIVES AND SWELLING OF EXTREMETIES. NOTE: TOLUENE
(108-88-3) APPEARS ON THE NAVY LIST OF OCCUPATIONAL CHEM REPROD
HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING
LATEST HAZ LIST INFO AND SAFE HANDLING AND EXPOSURE INFORMATION .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE: FLUSH WITH CLEAN WATER (LOW PRESSURE) FOR AT LEAST 15
MIN, OCCASIONALLY LIFTING EYELIDS. OBTAIN MEDICAL ATTENTION. SKIN:
REMOVE CONTAM CLTHG & WASH BEFORE RE-USE. WASH AFFECTED AREA WITH
SOAP AND WATER. INHAL: MOVE TO AREA FREE FROM FURTHER EXPOSURE.
ADMINISTER OXYGEN OR ARTF RESP AS NEEDED. OBTAIN MED ATTN. INGEST:
CONSULT PHYSICIAN. DO NOT INDUCE VOMITING.

Flash Point Method:TCC
Flash Point:40F,4.4C
Lower Limits:1.3%
Upper Limits:7%
Extinguishing Media:FOAM, DRY CHEMICAL, CO2 AND/OR WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DURING A FIRE, IRRIT & TOX GASES & SMOKE
ARE PRESENT FROM DECOMP. ISOLATE FROM HEAT/SPARKS/OPEN FLAMES. CLSD
CNTNRS MAY BURST WHEN EXPOSED TO EXTREME(SUPP DATA)

Spill Release Procedures:EVAC NON-ESSENTIAL PERSONNEL. REMOVE ALL
SOURCES OF IGNIT: VENT AREA. EQUIP CLEAN-UP CREW W/APPROP PROT
EQUIP. DIKE OR IMPOUND SPILLED MATL & CONTROL FURTHER SPILLAGE IF
FEASIBLE. NOTIFY APPROP AUTHOR ITIES IF NEC. COVER SPILL W/SAWDUST,
(SUPP DATA)
Neutralizing Agent:DECONTAM SOLNS: AMMOUNIUM HYDROXIDE (0-10%),
DETERGENT (2-5%) & BALANCE WATER.

Handling and Storage Precautions:STORAGE TEMP: MIN 32F/MAX 122F.
AVERAGE SHELF LIFE: 1 YR AT 77F. SENSITIVE TO HEAT, LIGHT,
MOISTURE.
Other Precautions:IF CNTNR IS EXPOSED TO EXTREME HEAT CNTNR CAN
PRESSURIZE & BURST. IF MOISTURE ENTERS CNTNR, PRESSURE CAN BUILD UP
DUE TO REACTION PRODUCING CO2, WHICH CAN CAUSE SEALED CNTNR TO
BURST. DO NOT RESEAL IF CONTAM IS SUSPECTED. KEEP AWAY (ING 5)

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPS THAT ARE APPRVD
FOR USE IN ISOCYANTE CNTNG ENVIORNMENTS, (AIR PURIFYING OR FRESH
AIR SUPPLIED). IN SPRAY APPLICATION, YOU MUST PROT AGAINST EXPOSURE
TO BOTH VAP & SPRAY M IST. OBSERVE OSHA REGS FOR RESP(ING 7)
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:CHEM RESISTANT GLOVES/NEOPRENE/HYPALONS
Eye Protection:CHEM WORK GOGG/FULL LENGTH FSHLD .
Other Protective Equipment:COVER AS MUCH AS THE EXPOSED AREA AS
POSSIBLE WITH APPROPRIATE CLTHG. SAFETY SHOWERS & EYE WASH STATIONS
SHLD BE AVAIL.
Work Hygienic Practices:EDUCATE AND TRAIN EMPLOYEES IN SAFE USE OF THE
PRODUCT. CNTCT LENSES SHDLD NOT BE WORN. IF SKIN CREAMS USED, (ING
19)
Supplemental Safety and Health
KEY1;T3.EXPLO HAZ: HEAT. VAPS FORM AN EXPLO MIX IN AIR BETWEEN THE
UPPER & LOWER EXPLO LIMITS. SPILL PROC: VERMICULITE/OTHER ABSORBENT
MATL, POUR LIQ DECONTAM OVER SPILLAGE & ALLOW TO REACT @ LST 10 M
INS. COLLECT MATL IN OPEN CNTNRS & ADD FURTHER AMTS OF DECONTAM
SOLN. REMOVE CNTNRS TO SAFE PLACE. COVER LOOSELY. (ING 4

HCC:T3
Boiling Pt:B.P. Text:230F,110C
Vapor Pres:22
Vapor Density:HVR/AIR
Spec Gravity:0.94 (H2O=1)
Evaporation Rate & Reference:FASTER (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:73

Stability Indicator/Materials to Avoid:YES
AVOID CNTCT W/WATER, ALCOHOLS, AMINES, STRONG BASES, METAL CMPNDS OR
SURFACE ACIVE AGENTS.
Stability Condition to Avoid:CONTACT WITH MOISTURE & OTHER MATERIALS
WHICH REACT WITH ISOCYANATES. TEMPERATURE ABOVE MAX STORAGE
TEMPERATURE.
Hazardous Decomposition Products:BY FIRE: CO2, CO, OXIDES OF NITROGEN,
TRACES OF HCN AND TDI.

Waste Disposal Methods:WASTE MATL MUST BE DISPOSED OF I/A/W FEDERAL,
STATE & LOC ENVIRONMENTAL CONTROL REGS. EMPTY CNTNRS MUST BE HNDLG
W/CARE DUE TO PROD RESIDUE & COMBUST SOLV VAPOR. DECONTAM CNTNRS
PRIOR TO DISPOSAL. DO NOT HEAT OR CUT EMPTY CNTNR W/ELEC OR GAS
TORCH.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.